Surface Properties and Catalysis by Non-Metals

Surface Properties and Catalysis by Non-Metals PDF Author: J.P. Bonnelle
Publisher: Springer Science & Business Media
ISBN: 9400971605
Category : Science
Languages : en
Pages : 571

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Book Description
In the field of heterogeneous catalysis. it is convenient to distinguish. in a perfectly unjustified and over··simplified way. bet:leen metal catalysts. 2nd the other catalysts. The fj.J"st are easy to define : they are those in which a reduced metal is the active phase. It is thus easy to circumscribe. by exclusion, the other class namely the "non-metals". We have adopted this definition for the sake of our colleagues working on catalysis by metals, and to avoid a lengthy title like "sm' face pl"operties and catalysts by transi tion metal oxides. sulftdes, carbides, nitriles, etc. Defined in this manner, non-metal catalysts represented, in 1980, 84 wt. % of the industrial heterogeneous catalysts. To be more specific, this proportion corresponds to catalysts which, under the working conditions in the industrial ?lant. contain their catalytically active metallic elements in a non-reduced state. It should however be recalled that most metal catalysts are supported on oxides, which, often, repl'esent over 90% (sometimes 99.4% in the case of the platinum reforming catalysts) of the total weight.

Surface Properties and Catalysis by Non-Metals

Surface Properties and Catalysis by Non-Metals PDF Author: J.P. Bonnelle
Publisher: Springer Science & Business Media
ISBN: 9400971605
Category : Science
Languages : en
Pages : 571

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Book Description
In the field of heterogeneous catalysis. it is convenient to distinguish. in a perfectly unjustified and over··simplified way. bet:leen metal catalysts. 2nd the other catalysts. The fj.J"st are easy to define : they are those in which a reduced metal is the active phase. It is thus easy to circumscribe. by exclusion, the other class namely the "non-metals". We have adopted this definition for the sake of our colleagues working on catalysis by metals, and to avoid a lengthy title like "sm' face pl"operties and catalysts by transi tion metal oxides. sulftdes, carbides, nitriles, etc. Defined in this manner, non-metal catalysts represented, in 1980, 84 wt. % of the industrial heterogeneous catalysts. To be more specific, this proportion corresponds to catalysts which, under the working conditions in the industrial ?lant. contain their catalytically active metallic elements in a non-reduced state. It should however be recalled that most metal catalysts are supported on oxides, which, often, repl'esent over 90% (sometimes 99.4% in the case of the platinum reforming catalysts) of the total weight.

Catalysis by Nonmetals

Catalysis by Nonmetals PDF Author: Oleg V. Krylov
Publisher: Academic Press
ISBN: 1483191753
Category : Science
Languages : en
Pages : 296

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Book Description
Catalysis by Non-metals: Rules of Catalyst Selection presents the development of scientific principles for the collection of catalysts. It discusses the investigation of the mechanism of chemosorption and catalysis. It addresses a series of properties of solid with catalytic activity. Some of the topics covered in the book are the properties of a solid and catalytic activity in oxidation-reduction reactions; the difference of electronegativities and the effective charges of atoms; the role of d-electrons in the catalytic properties of a solid; the color of solids; and proton-acid and proton-base properties of a surface. The catalytic activity and structure of solids are covered. The type of crystal lattice and crystalline lattice parameters are discussed. The text describes the decomposition of alcohols. A study of the dehydrogenation and hydrogenation reactions is presented. A chapter is devoted to the decomposition of inorganic hydrides. Another section focuses on the hydrogen-deuterium exchange and other simple reactions. The book can provide useful information to scientists, physicists, students, and researchers.

Electrocatalysis on Non-metallic Surfaces

Electrocatalysis on Non-metallic Surfaces PDF Author: Alan D. Franklin
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 396

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Book Description


Metal Oxides in Heterogeneous Catalysis

Metal Oxides in Heterogeneous Catalysis PDF Author: Jacques C. Vedrine
Publisher: Elsevier
ISBN: 0128116323
Category : Technology & Engineering
Languages : en
Pages : 618

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Book Description
Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications

Surface Science

Surface Science PDF Author: Fernando A. Ponce
Publisher: Springer Science & Business Media
ISBN: 3642763766
Category : Technology & Engineering
Languages : en
Pages : 491

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Book Description
In this book "surface science" is understood in a broad sense, taken to include two-dimensional structures such as thin films and superlattices. Thecontributions reflect current research activities in surface and thin-film science in Latin-America, presenting a clear picture of the research centers, equipment and expertise available in the region in this rapidly developing field of physics. The topics treated cover the whole spectrum of the subject, with the latest theoretical results beingreported alongside details of industrial applications such as materials characterization and photovoltaic cells. Surface scientists, engineers and research admistrators will find this volume of interest.

Metal Oxide Catalysis, 2 Volume Set

Metal Oxide Catalysis, 2 Volume Set PDF Author: S. David Jackson
Publisher: John Wiley & Sons
ISBN: 3527626123
Category : Science
Languages : en
Pages : 887

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Book Description
With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.

Adsorption and Catalysis on Transition Metals and Their Oxides

Adsorption and Catalysis on Transition Metals and Their Oxides PDF Author: Vsevolod F. Kiselev
Publisher: Springer Science & Business Media
ISBN: 3642738877
Category : Technology & Engineering
Languages : en
Pages : 453

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Book Description
This book deals with adsorption and catalysis on the surface of transition elements and their compounds, many of which are in teresting because of their particular electronic structure. The authors have worked through a vast body of experimental evi dence on the structure and properties of surfaces of transition metals and relevant oxides. Consideration is given mostly to simple (as opposed to mixed) oxides of transition elements, to common metals and to the adsorption of simple gases. A great deal of attention is paid to the nature of active surface sites responsible for chemisorption and catalytic transformations. The description relies mainly on the simplified ligand-field theory, which, however, proves quite satisfactory for predicting the adsorptive and catalytic activity of species. In many cases simple systems were explored with the aid of novel techniques, and it is only for such systems that the mechanism of the ele mentary act of adsorption and catalysis can be given adequate treatment. The present monograph has emerged from our earlier work in Russian, which appeared in the Khimiya Publishing House (Mos cow) in 1981. This English edition has, however, been revised completely to broaden its scope and to include more recent a chievements. For fruitful discussions the authors are grateful to A.A.

Advances in Catalysis

Advances in Catalysis PDF Author:
Publisher: Academic Press
ISBN: 9780080565378
Category : Technology & Engineering
Languages : en
Pages : 395

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Book Description
Advances in Catalysis

Catalysis

Catalysis PDF Author: James J Spivey
Publisher: Royal Society of Chemistry
ISBN: 1847553222
Category : Technology & Engineering
Languages : en
Pages : 192

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Book Description
There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

Preparation of Catalysts VI

Preparation of Catalysts VI PDF Author: G. Poncelet
Publisher: Elsevier
ISBN: 9780080544663
Category : Science
Languages : en
Pages : 1181

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Book Description
The organizers of this Sixth Symposium maintained their initial objectives, namely to gather experts from both industries and universities to discuss the scientific problems involved in the preparation of heterogeneous catalysts, and to encourage as much as possible the presentation of research work on catalysts of real industrial significance. Another highlight of these symposia is to reserve a substantial part of the program to new developments in catalyst preparation, new preparation methods and new catalytic systems. The fact that chemical reactions which were hardly conceivable some years ago have become possible today through the development of appropriate catalytic systems proves that catalysis is in constant progress. The papers in this volume deal with preparation of new catalysts and supports, catalyst preparation via sol-gel methods, supported catalysts and synthesis of nanometer size catalysts.