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Author: Jiro Tsuji
Publisher: Springer Science & Business Media
ISBN: 9783540239826
Category : Science
Languages : en
Pages : 348
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Book Description
with contributions by numerous experts
Author: Jiro Tsuji
Publisher: Springer Science & Business Media
ISBN: 9783540239826
Category : Science
Languages : en
Pages : 348
Get Book
Book Description
with contributions by numerous experts
Author: Ei-ichi Negishi
Publisher: John Wiley & Sons
ISBN: 0471461555
Category : Science
Languages : en
Pages : 1698
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Book Description
Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
Author: Jiro Tsuji
Publisher: Springer Science & Business Media
ISBN: 3642674755
Category : Science
Languages : en
Pages : 221
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Book Description
Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-
Author: Jiro Tsuji
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 596
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Book Description
Basic chemistry of organopalladium compounds; Classification of the reactions involving Pd(II) compounds and Pd(O) complexes.
Author: Richard F. Heck
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 504
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Book Description
Author: Peter J. H. Scott
Publisher: John Wiley & Sons
ISBN: 1118336704
Category : Science
Languages : en
Pages : 184
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Book Description
Integrates solid-phase organic synthesis with palladiumchemistry The Wiley Series on Solid-Phase Organic Syntheses keepsresearchers current with major accomplishments in solid-phaseorganic synthesis, providing full experimental details. Followingthe validated, tested, and proven experimental procedures, readerscan easily perform a broad range of complex syntheses needed fortheir own experiments and industrial applications. The series isconveniently organized into themed volumes according to thespecific type of synthesis. This second volume in the series focuses on palladium chemistryin solid-phase synthesis, exploring palladium catalysts andreactions, procedures for preparation and utilization, ligands, andlinker reactions. The first part of the volume offers acomprehensive overview of the field. Next, the chapters areorganized into three parts: Part Two: Palladium-Mediated Solid-Phase Organic Syntheses Part Three: Immobilized Catalysts and Ligands Part Four: Palladium-Mediated Multifunctional Cleavage Each chapter is written by one or more leading internationalexperts in palladium chemistry. Their contributions reflect athorough examination and review of the current literature as wellas their own first-hand laboratory experience. References at theend of each chapter serve as a gateway to the field'sliterature. The introduction of palladium-mediated, cross-coupling reactionsmore than thirty years ago revolutionized the science ofcarbon-carbon bond formation. It has now become a cornerstone oftoday's synthetic organic chemistry laboratory. With this volume,researchers in organic and medicinal chemistry have access to asingle resource that explains the fundamentals of palladiumchemistry in solid-phase synthesis and sets forth clear,step-by-step instructions for conducting their own syntheses.
Author: Peter Maitlis
Publisher: Elsevier
ISBN: 0323159613
Category : Science
Languages : en
Pages : 232
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Book Description
The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.
Author: Jiro Tsuji
Publisher: John Wiley & Sons
ISBN: 0470021195
Category : Science
Languages : en
Pages : 670
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Book Description
Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.
Author: Jie Jack Li
Publisher: Elsevier
ISBN: 9780080437057
Category : Science
Languages : en
Pages : 436
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Book Description
For this text, Jack Li and Gordon Gribble have compiled an array of referenced examples of the use of palladium in heterocyclic chemistry.
Author: J. Tsuji
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 340
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Book Description
Perspectives in Organopalladium Chemistry for the 21st Century is a monograph on modern organopalladium chemistry, with an emphasis on the use of palladium in organic synthesis. The collection of articles is reprinted from a special issue of the Journal of Organometallic Chemistry. The field of organopalladium chemistry is evolving rapidly, building on a growing catalogue of reactions that employ palladium-containing catalysts. This book should hold particular interest for those who apply palladium reagents and catalysts to organic synthesis; in fact, palladium is considered by many to be the most useful transition element employed for organic syntheses. This selection of articles by leading scientists, published as "Perspectives in Organopalladium Chemistry for the 21st Century", provides an impressive overview of the field that every chemist who works with organometallic palladium catalysts should read.
