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Author: Thomas Wirth
Publisher: Springer Science & Business Media
ISBN: 3540441077
Category : Medical
Languages : en
Pages : 275
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Book Description
T. Wirth: Introduction and General Aspects.- M. Ochiai: Reactivities, Properties and Structures.- A. Varvoglis: Preparation of Hypervalent Iodine Compounds.- V.V. Zhdankin: C-C-Bond Forming Reactions.- G.F. Koser: C- Heteroatom-Bond Forming Reactions.- G.F. Koser: Heteroatom- Heteroatom-Bond Forming Reactions.- T. Wirth: Oxidations and Rearrangements.- H. Tohma, Y. Kita: Synthetic Applications (Total Synthesis and Natural Product Synthesis).
Author: Thomas Wirth
Publisher: Springer Science & Business Media
ISBN: 3540441077
Category : Medical
Languages : en
Pages : 275
Get Book
Book Description
T. Wirth: Introduction and General Aspects.- M. Ochiai: Reactivities, Properties and Structures.- A. Varvoglis: Preparation of Hypervalent Iodine Compounds.- V.V. Zhdankin: C-C-Bond Forming Reactions.- G.F. Koser: C- Heteroatom-Bond Forming Reactions.- G.F. Koser: Heteroatom- Heteroatom-Bond Forming Reactions.- T. Wirth: Oxidations and Rearrangements.- H. Tohma, Y. Kita: Synthetic Applications (Total Synthesis and Natural Product Synthesis).
Author: Viktor V. Zhdankin
Publisher: John Wiley & Sons
ISBN: 1118341309
Category : Science
Languages : en
Pages : 480
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Book Description
Hypervalent Iodine Chemistry is the first comprehensivetext covering all of the main aspects of the chemistry of organicand inorganic polyvalent iodine compounds, including applicationsin chemical research, medicine, and industry. Providing a comprehensive overview of the preparation,properties, and synthetic applications of this important class ofreagents, the text is presented in the following way: The introductory chapter provides a historicalbackground and describes the general classification ofiodine compounds, nomenclature, hypervalent bonding, structuralfeatures, and the principles of reactivity of polyvalent iodinecompounds. Chapter 2 gives a detailed description of thepreparative methods and structural features of all knownclasses of organic and inorganic derivatives of polyvalentiodine. Chapter 3, the key chapter of the book, deals with themany applications of hypervalent iodine reagents in organicsynthesis. Chapter 4 describes the most recent achievementsin hypervalent iodine catalysis. Chapter 5 deals with recyclable polymer-supportedand nonpolymeric hypervalent iodine reagents. Chapter 6 covers the "green" reactions ofhypervalent iodine reagents under solvent-free conditions or inaqueous solutions. The final chapter provides an overview of the importantpractical applications of polyvalent iodine compounds inmedicine and industry. This book is aimed at all chemists interested in iodinecompounds, including academic and industrial researchers ininorganic, organic, physical, medicinal, and biological chemistry.It will be particularly useful to synthetic organic and inorganicchemists, including graduate and advanced undergraduate students.It comprehensively covers the green chemistry aspects ofhypervalent iodine chemistry, making it especially useful forindustrial chemists.
Author: Kazuaki Ishihara
Publisher: John Wiley & Sons
ISBN: 3527348298
Category : Technology & Engineering
Languages : en
Pages : 452
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Book Description
Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.
Author: A. Varvoglis
Publisher: Academic Press
ISBN: 0080534368
Category : Science
Languages : en
Pages : 223
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Book Description
This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Key Features * Features up-to-date coverage of a wide range of topics * Includes many tables featuring a diversity of reactivity, and a comprehensive index * Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry * Contains a section on unusual efficiency of hypervalent iodine reactions
Author: Tatsuo Kaiho
Publisher: John Wiley & Sons
ISBN: 1118878655
Category : Science
Languages : en
Pages : 512
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Book Description
This book comprehensively covers iodine, its chemistry, and itsrole in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodinechemistry with discussion on elemental aspects: characteristics,properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how tosynthesize complex compounds using iodine reagents orintermediates • Describes traditional and modern processingtechniques, such as starch, cupper, blowing out, and ion exchangeresin methods • Includes seven detailed sections devoted to theapplications of iodine: Characteristics, Production, Synthesis,Biological Applications, Industrial Applications, BioorganicChemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalentiodine-mediated cross coupling reactions, agrochemicals, dyesensitized solar cells, and therapeutic agents
Author: Kin-ya Akiba
Publisher: John Wiley & Sons
ISBN: 9780471240198
Category : Science
Languages : en
Pages : 438
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Book Description
Eine umfassende Einführung in das Gebiet der hypervalenten Moleküle und anschauliche Darstellung grundlegender Aufbauprinzipien von Verbindungen der Hauptgruppenelemente und metallorganischen Spezies. Gleichermaßen tiefgründig behandelt werden organische Verbindungen, beispielsweise von Silicium, Phosphor, Schwefel und Iod, und anorganische Moleküle, die unter anderem Antimon, Zinn und Lithium enthalten. (12/98)
Author: Thomas Baumgartner
Publisher: John Wiley & Sons
ISBN: 1119235979
Category : Science
Languages : en
Pages : 557
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Book Description
Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards Functional Hybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.
Author: Berit Olofsson
Publisher: John Wiley & Sons
ISBN: 1119352304
Category : Science
Languages : de
Pages : 1068
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Book Description
The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Author: Thomas Wirth
Publisher: Springer
ISBN: 3319337335
Category : Science
Languages : en
Pages : 320
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Book Description
The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.
Author: Thomas Wirth
Publisher: John Wiley & Sons
ISBN: 3527641955
Category : Science
Languages : en
Pages : 441
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Book Description
Selenium-based methods in synthetic chemistry have developed rapidly over the past years and are now offering highly useful tools for organic synthesis. Filling the gap for a comprehensive handbook and ready reference, this book covers all modern developments within the field, including biochemical aspects. The chemistry chapters are organized according to the different reactivities of various selenium compounds and reagents, with each chapter dealing with a special reaction type. Also includes a table with 77Se NMR shifts to aid in practical problems. From the Contents: * Electrophilic and Nucleophilic Selenium * Selenium Compounds in Radical Reactions * Selenium-Stabilized Carbanions * Selenium Compounds with Valency Higher than Two * Selenocarbonyls * Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement * Selenium Compounds as Ligands and Catalysts * Biological and Biochemical Aspects of Selenium Compounds
