Homogeneous Catalysis

Homogeneous Catalysis PDF Author: Sumit Bhaduri
Publisher: John Wiley & Sons
ISBN: 1118872479
Category : Science
Languages : en
Pages : 288

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Book Description
Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts

Homogeneous Catalysis

Homogeneous Catalysis PDF Author: Sumit Bhaduri
Publisher: John Wiley & Sons
ISBN: 1118872479
Category : Science
Languages : en
Pages : 288

Get Book

Book Description
Over the last decade, the area of homogeneous catalysis withtransition metal has grown in great scientific interest andtechnological promise, with research in this area earning threeNobel Prizes and filing thousands of patents relating tometallocene and non-metallocene single site catalysts, asymmetriccatalysis, carbon-carbon bond forming metathesis and cross couplingreactions. This text explains these new developments in a unified, cogent, andcomprehensible manner while also detailing earlier discoveries andthe fundamentals of homogeneous catalysis. Serving as a self-studyguide for students and all chemists seeking to gain entry into thisfield, it can also be used by experienced researchers from bothacademia and industry for referring to leading state of the artreview articles and patents, and also as a quick self-study manualin an area that is outside their immediate expertise. The bookfeatures: • Topics including renewable feed stocks (biofuel,glycerol), carbon dioxide based processes (polycarbonates),fluorous solvents, ionic liquid, hydroformylation, polymerization,oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry,homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (casestudies), and examples from proven industrial processes with cleardiscussions on environmental and techno-commercial issues • Extensive references to cutting edge research withapplication potential and leading patents • Tables and illustrations to help explain difficultconcepts

Homogeneous Catalysts

Homogeneous Catalysts PDF Author: John C. Chadwick
Publisher: John Wiley & Sons
ISBN: 3527636005
Category : Science
Languages : en
Pages : 592

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Book Description
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.

Heterogenized Homogeneous Catalysts for Fine Chemicals Production

Heterogenized Homogeneous Catalysts for Fine Chemicals Production PDF Author: Pierluigi Barbaro
Publisher: Springer Science & Business Media
ISBN: 9789048136964
Category : Science
Languages : en
Pages : 462

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Book Description
Table 1 E factors (tonnes of waste generated per tonne of product manufactured [7] Industry segment Annual product tonnage E factor 6 8 Oil refining 10 –10 Approx. 0. 1 4 6 Bulk chemicals 10 –10

Computational Modeling of Homogeneous Catalysis

Computational Modeling of Homogeneous Catalysis PDF Author: Feliu Maseras
Publisher: Springer Science & Business Media
ISBN: 0306477181
Category : Science
Languages : en
Pages : 368

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Book Description
Recent results on a wide array of catalytic processes are collected in this volume. The book illustrates the importance of computational modelling in homogeneous catalysis by providing up-to-date reviews of its application to a variety of reactions of industrial interest.

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis PDF Author: S. Ted Oyama
Publisher: Elsevier
ISBN: 9780080558011
Category : Technology & Engineering
Languages : en
Pages : 528

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Book Description
The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Carbon Dioxide Electrochemistry

Carbon Dioxide Electrochemistry PDF Author: Marc Robert
Publisher: Royal Society of Chemistry
ISBN: 1788015460
Category : Science
Languages : en
Pages : 461

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Book Description
Homogeneous and Heterogeneous Catalysis

Homogeneous Catalysis with Metal Complexes

Homogeneous Catalysis with Metal Complexes PDF Author: Gheorghe Duca
Publisher: Springer Science & Business Media
ISBN: 364224629X
Category : Science
Languages : en
Pages : 484

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Book Description
The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.

Bridging Heterogeneous and Homogeneous Catalysis

Bridging Heterogeneous and Homogeneous Catalysis PDF Author: Can Li
Publisher: John Wiley & Sons
ISBN: 3527675922
Category : Technology & Engineering
Languages : en
Pages : 1091

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Book Description
There are two main disciplines in catalysis research -- homogeneous and heterogeneous catalysis. This is due to the fact that the catalyst is either in the same phase (homogeneous catalysis) as the reaction being catalyzed or in a different phase (heterogeneous catalysis). Over the past decade, various approaches have been implemented to combine the advantages of homogeneous catalysis (efficiency, selectivity) with those of heterogeneous catalysis (stability, recovery) by the heterogenization of homogeneous catalysts or by carrying out homogeneous reactions under heterogeneous conditions. This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts. As such, it highlights structural analogies and shows mechanistic parallels between the two, while additionally presenting kinetic analysis methods and models that either work for both homogeneous and heterogeneous catalysis. Chapters cover asymmetric, emulsion, phase-transfer, supported homogeneous, and organocatalysis, as well as in nanoreactors and for specific applications, catalytic reactions in ionic liquids, fluorous and supercritical solvents and in water. Finally, the text includes computational methods for investigating structure-reactivity relations. With its wealth of information, this invaluable reference provides academic and industrial chemists with novel concepts for innovative catalysis research.

Enantioselective Homogeneous Supported Catalysis

Enantioselective Homogeneous Supported Catalysis PDF Author: Radovan Šebesta
Publisher:
ISBN: 9781849731768
Category : Science
Languages : en
Pages : 0

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Book Description
This book covers the most important concepts of homogeneous supported catalysis with an emphasis on enantioselective processes. It describes the state-of-the-art and latest developments in each area while critically evaluating the strengths and weaknesses of this important method.

Homogeneous Catalysis with Compounds of Rhodium and Iridium

Homogeneous Catalysis with Compounds of Rhodium and Iridium PDF Author: R. Dickson
Publisher: Springer Science & Business Media
ISBN: 9789027718808
Category : Science
Languages : en
Pages : 306

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Book Description
Some years ago, I agreed to contribute a volume to the Academic Press 'Organo metallic Chemistry' series - the metals to be covered were rhodium and iridium. Initially, my plan was to discuss both the fundamental organometallic chemistry and applications in organic synthesis. When the first draft of the manuscript was complete, it was apparent that I had exceeded my allowance of pages by a huge amount. It was then that I decided that the catalysis section warranted separate treatment. I am grateful to Reidel for agreeing to publish this volume on Homogeneous Catalysis with Compounds of Rhodium and Iridium as part of their 'Catalysis by Metal Complexes' series. The material I had for the original Academic Press project covered the litera ture to the end of 1978. I decided to update this to the end of 1982 with a few key references from 1983. It is some measure of the rate of progress in this field that the number of references almost doubled during this revision.