Chromium Oxidations in Organic Chemistry PDF Download
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Author: G. Cainelli
Publisher: Springer Science & Business Media
ISBN: 3642693628
Category : Science
Languages : en
Pages : 272
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Book Description
Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .
Author: G. Cainelli
Publisher: Springer Science & Business Media
ISBN: 3642693628
Category : Science
Languages : en
Pages : 272
Get Book
Book Description
Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .
Author: G Cainelli
Publisher:
ISBN: 9783642693632
Category :
Languages : en
Pages : 280
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Book Description
Author: Raj K. Bansal
Publisher: Jones & Bartlett Learning
ISBN: 9780763706654
Category : Science
Languages : en
Pages : 436
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Book Description
Designed for undergraduate and beginning graduate courses in organic synthesis.
Author: Donald G. Lee
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 200
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Book Description
Author: Gabriel Tojo
Publisher: Springer Science & Business Media
ISBN: 038725725X
Category : Science
Languages : en
Pages : 388
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Book Description
The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.
Author: Barry M. Trost
Publisher: Elsevier
ISBN: 9780080405988
Category : Science
Languages : en
Pages : 1048
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Book Description
Volume 7.
Author: Walter Trahanovsky
Publisher: Elsevier
ISBN: 0323158714
Category : Science
Languages : en
Pages : 262
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Book Description
Organic Chemistry, Volume 5-B: Oxidation in Organic Chemistry, Part B presents some of the most common and significant reactions in organic chemistry, which involves oxidation and reduction. This book provides detailed discussions of specific oxidants or topics concerning oxidation of organic compounds. Organized into four chapters, this volume begins with an overview of the specific oxidants, including thallium(III), cupric ion, and ruthenium tetroxide. This text then presents the scope and preparative use as well as the mechanistic aspects of the various oxidations. Other chapters consider the significance of phenolic oxidative coupling in nature's biosynthetic pathways. This book discusses as well the various mechanistic alternatives for the enzymic and non-enzymic reactions, which will lead to a fuller understanding of the enzymic mechanisms and the greater synthetic utility of this reaction. The final chapter deals with the oxidative coupling of phenols. This book is a valuable resource for organic chemists and research workers.
Author: S. Sundaram
Publisher: Springer
ISBN: 9783642208188
Category : Science
Languages : en
Pages : 66
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Book Description
Chromic acid and chromium oxide are the two versatile Cr(VI) oxidants known to organic chemists for decades. The introduction of the Core's reagent , viz: pyridinium chlorochromate, in 1975 followed by the publications on several Cr(VI) oxidizing agents containing the -onium chromates and halochromates in the last three decades have very much changed the chemistry of oxidations with Chromium VI. Several of these new reagents have been shown to be mild so that they can be handled easily and the reacton products may also be controlled. Some of them are highly selective oxidants for positions like allylic hydroxylic group, etc., and some other are highly regioselective. The information on more than 36 such reagents reported in various internationally reputed journals spanning about 280 references have been collected and provided in this book in such a manner that it will be very useful for professionals, researchers, teachers and graduate students working in organic synthesis.
Author: Milos Hudlicky
Publisher: Wiley-VCH
ISBN:
Category : Science
Languages : en
Pages : 464
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Book Description
A complete source of information on oxidations of organic compounds, with emphasis on preparative aspects and results. Important features include: discussions on oxidizing agents and on oxidation reactions using them; correlation tables showing what oxidizing agents are suitable for conversions of particular compounds to their oxidation products; and a collection of typical laboratory procedures for the main types of oxidations. All information is supported by examples, thorough referencing, and indexing.
Author: Kenneth B. Wiberg
Publisher:
ISBN:
Category : Chemistry, Organic
Languages : en
Pages : 466
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Book Description
